Nanoparticle induced formation of self-assembled zwitterionic surfactant microdomains which mimic microemulsions for the: In situ fabrication and dispersion of silver nanoparticles

Taichi Nakagawa; Akihide Hibara; Willie L. Hinze; Yoshitaka Takagai

doi:10.1039/d0ra06824a

Nanoparticle induced formation of self-assembled zwitterionic surfactant microdomains which mimic microemulsions for the: In situ fabrication and dispersion of silver nanoparticles

Taichi Nakagawa, Akihide Hibara, Willie L. Hinze, Yoshitaka Takagai

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The effective synthesis of highly concentrated and stable spherical silver nanoparticles (Ag-NPs) enclosed within microdomains formed by the Ag-NP induced self-assembly of zwitterionic surfactants is described. In this paper, the rapid and efficient synthesis of dispersed and stable Ag-NPs in zwitterionic surfactants, such as 3-(nonyldimethylammonio)- or 3-(decyldimethyl-ammonio)-propyl sulfate (C9- or C10-APSO4) that self-assemble in the presence of the Ag-NPs to form microdomains akin to microemulsions (ME) without the need of any organic solvent, co-surfactant or polymer is presented. Essentially all (>99.9%) of the synthesized Ag-NPs (TEM diameter 16.8 ± 4.3 nm) were incorporated and dispersed within the ME microdomains (213.5 ± 48.0 nm). A mechanism for formation of ME and its enclosing of the Ag-NPs in the ME is proposed. This journal is

Original language	English
Pages (from-to)	34161-34166
Number of pages	6
Journal	RSC Advances
Volume	10
Issue number	56
DOIs	https://doi.org/10.1039/d0ra06824a
Publication status	Published - 2020 Sep 15
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

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Nanoparticle induced formation of self-assembled zwitterionic surfactant microdomains which mimic microemulsions for the : In situ fabrication and dispersion of silver nanoparticles. / Nakagawa, Taichi; Hibara, Akihide; Hinze, Willie L.; Takagai, Yoshitaka.

In: RSC Advances, Vol. 10, No. 56, 15.09.2020, p. 34161-34166.

Research output: Contribution to journal › Article › peer-review

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abstract = "The effective synthesis of highly concentrated and stable spherical silver nanoparticles (Ag-NPs) enclosed within microdomains formed by the Ag-NP induced self-assembly of zwitterionic surfactants is described. In this paper, the rapid and efficient synthesis of dispersed and stable Ag-NPs in zwitterionic surfactants, such as 3-(nonyldimethylammonio)- or 3-(decyldimethyl-ammonio)-propyl sulfate (C9- or C10-APSO4) that self-assemble in the presence of the Ag-NPs to form microdomains akin to microemulsions (ME) without the need of any organic solvent, co-surfactant or polymer is presented. Essentially all (>99.9%) of the synthesized Ag-NPs (TEM diameter 16.8 ± 4.3 nm) were incorporated and dispersed within the ME microdomains (213.5 ± 48.0 nm). A mechanism for formation of ME and its enclosing of the Ag-NPs in the ME is proposed. This journal is ",

author = "Taichi Nakagawa and Akihide Hibara and Hinze, {Willie L.} and Yoshitaka Takagai",

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Nanoparticle induced formation of self-assembled zwitterionic surfactant microdomains which mimic microemulsions for the: In situ fabrication and dispersion of silver nanoparticles

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