Nanocrystallization of Insoluble Copper(I) Complex and Formation Mechanism

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5 Citations (Scopus)

Abstract

We have successfully fabricated insoluble copper(I) complex [Cu(-I)dppet]2 nanocrystals by developing the heterogeneous reaction process between rod-like nanocrystals of dppet ligand prepared in advance and added acetonitrile solution of copper(I) halide. During this reaction process, the shape of dppet ligand nanocrystals was dramatically changed from rod-like to spherical. Probably, the complexation reaction and subsequent nanocrystallization would proceed on or near swollen surface of dppet nanocrystals in acetonitrile droplet as restricted reaction field.

Original languageEnglish
Pages (from-to)150-155
Number of pages6
JournalMolecular crystals and liquid crystals
Volume621
Issue number1
DOIs
Publication statusPublished - 2015 Nov 2

Keywords

  • Copper(I) complexes
  • heterogeneous reaction process
  • nanocrystals
  • restricted reaction field

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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