Nanocrystallization of Insoluble Copper(I) Complex and Formation Mechanism

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    5 Citations (Scopus)

    Abstract

    We have successfully fabricated insoluble copper(I) complex [Cu(-I)dppet]2 nanocrystals by developing the heterogeneous reaction process between rod-like nanocrystals of dppet ligand prepared in advance and added acetonitrile solution of copper(I) halide. During this reaction process, the shape of dppet ligand nanocrystals was dramatically changed from rod-like to spherical. Probably, the complexation reaction and subsequent nanocrystallization would proceed on or near swollen surface of dppet nanocrystals in acetonitrile droplet as restricted reaction field.

    Original languageEnglish
    Pages (from-to)150-155
    Number of pages6
    JournalMolecular crystals and liquid crystals
    Volume621
    Issue number1
    DOIs
    Publication statusPublished - 2015 Nov 2

    Keywords

    • Copper(I) complexes
    • heterogeneous reaction process
    • nanocrystals
    • restricted reaction field

    ASJC Scopus subject areas

    • Chemistry(all)
    • Materials Science(all)
    • Condensed Matter Physics

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