Nanocrystallization of diarylethene and photochromic properties

Norio Tagawa; Akito Masuhara; Hitoshi Kasai; Hachiro Nakanishi; Hidetoshi Oikawa

doi:10.1021/cg100441h

Nanocrystallization of diarylethene and photochromic properties

Norio Tagawa, Akito Masuhara, Hitoshi Kasai, Hachiro Nakanishi, Hidetoshi Oikawa

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

We have succeeded, for the first time, in fabrication of diarylethene (DAE), 1,2-bis(2,4-dimethyl-5-phenyl-3-thienyl)-perfluorocyclopentene, nanocrystals using two nanocrystallization processes based on the reprecipitation method. Process I was the microwave irradiation after reprecipitation step. Process II uses a nucleating agent of a closed-DAE molecule without microwave irradiation. The crystal structure of the obtainedDAEnanocrystals was elucidated as the lattice structure of an open-DAE bulk crystal. Moreover, the DAE nanocrystals clearly exhibited photochromism by alternate irradiation of UV and visible light.

Original language	English
Pages (from-to)	2857-2859
Number of pages	3
Journal	Crystal Growth and Design
Volume	10
Issue number	7
DOIs	https://doi.org/10.1021/cg100441h
Publication status	Published - 2010 Jul 7

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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abstract = "We have succeeded, for the first time, in fabrication of diarylethene (DAE), 1,2-bis(2,4-dimethyl-5-phenyl-3-thienyl)-perfluorocyclopentene, nanocrystals using two nanocrystallization processes based on the reprecipitation method. Process I was the microwave irradiation after reprecipitation step. Process II uses a nucleating agent of a closed-DAE molecule without microwave irradiation. The crystal structure of the obtainedDAEnanocrystals was elucidated as the lattice structure of an open-DAE bulk crystal. Moreover, the DAE nanocrystals clearly exhibited photochromism by alternate irradiation of UV and visible light.",

author = "Norio Tagawa and Akito Masuhara and Hitoshi Kasai and Hachiro Nakanishi and Hidetoshi Oikawa",

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AU - Tagawa, Norio

AU - Masuhara, Akito

AU - Kasai, Hitoshi

AU - Nakanishi, Hachiro

AU - Oikawa, Hidetoshi

PY - 2010/7/7

Y1 - 2010/7/7

N2 - We have succeeded, for the first time, in fabrication of diarylethene (DAE), 1,2-bis(2,4-dimethyl-5-phenyl-3-thienyl)-perfluorocyclopentene, nanocrystals using two nanocrystallization processes based on the reprecipitation method. Process I was the microwave irradiation after reprecipitation step. Process II uses a nucleating agent of a closed-DAE molecule without microwave irradiation. The crystal structure of the obtainedDAEnanocrystals was elucidated as the lattice structure of an open-DAE bulk crystal. Moreover, the DAE nanocrystals clearly exhibited photochromism by alternate irradiation of UV and visible light.

AB - We have succeeded, for the first time, in fabrication of diarylethene (DAE), 1,2-bis(2,4-dimethyl-5-phenyl-3-thienyl)-perfluorocyclopentene, nanocrystals using two nanocrystallization processes based on the reprecipitation method. Process I was the microwave irradiation after reprecipitation step. Process II uses a nucleating agent of a closed-DAE molecule without microwave irradiation. The crystal structure of the obtainedDAEnanocrystals was elucidated as the lattice structure of an open-DAE bulk crystal. Moreover, the DAE nanocrystals clearly exhibited photochromism by alternate irradiation of UV and visible light.

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Nanocrystallization of diarylethene and photochromic properties

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