NaCuMoO4(OH) as a candidate frustrated J1-J2 Chain Quantum Magnet

Kazuhiro Nawa, Yoshihiko Okamoto, Akira Matsuo, Koichi Kindo, Yoko Kitahara, Syota Yoshida, Shohei Ikeda, Shigeo Hara, Takahiro Sakurai, Susumu Okubo, Hitoshi Ohta, Zenji Hiroi

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23 Citations (Scopus)


In a frustrated J1-J2 chain with the nearest-neighbor ferromagnetic interaction J1 and the next-nearest-neighbor antiferromagnetic interaction J2, novel magnetic states such as a spin-nematic state are theoretically expected. However, they have been rarely examined in experiments because of the difficulty in obtaining suitable model compounds. We show here that the quasi-one-dimensional antiferromagnet NaCuMoO4(OH), which comprises edge-sharing CuO2 chains, is a good candidate J1-J2 chain antiferromagnet. The exchange interactions are estimated as J1 = ?51K and J2 = 36K by comparing the magnetic susceptibility, heat capacity, and magnetization data with the data obtained using calculations by the exact diagonalization method. High-field magnetization measurements at 1.3K show a saturation above 26 T with little evidence of a spin nematic state expected just below the saturation field, which is probably due to smearing effects caused by thermal fluctuations and the polycrystalline nature of the sample.

Original languageEnglish
Article number103702
Journaljournal of the physical society of japan
Issue number10
Publication statusPublished - 2014 Oct 15
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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