N-benzyl-2,3-oxazolidinone as a glycosyl donor for selective α-glycosylation and one-pot oligosaccharide synthesis involving 1,2-cis-glycosylation

Shino Manabe, Kazuyuki Ishii, Yukishige Ito

Research output: Contribution to journalArticlepeer-review

133 Citations (Scopus)

Abstract

Glycosylation reactions using N-benzyl-2,3-trans-oxazolidinones as the glycosyl donors were shown to be highly α-selective. Advantages of the donor include facile preparation in gram-scale preparation and simple deprotection procedures. Subsequently, a one-pot oligosaccharide synthesis involving 1,2-cis glycosidic linkages was demonstrated using the novel glycosyl donors.

Original languageEnglish
Pages (from-to)10666-10667
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number33
DOIs
Publication statusPublished - 2006 Aug 23
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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