N-Allenylnitrone acts as 2-azadiene in the Cu-catalyzed cascade reaction of O-propargylic oximes with azodicarboxylates

Itaru Nakamura, Takeru Jo, Dong Zhang, Masahiro Terada

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

The reaction of O-propargylic oximes with azodicarboxylates efficiently afforded 1,2,4-triazine oxides in good yields. The key intermediate, N-allenylnitrone, acted as 2-azadiene, undergoing stepwise [4 + 2] cycloaddition.

Original languageEnglish
Pages (from-to)914-918
Number of pages5
JournalOrganic Chemistry Frontiers
Volume1
Issue number8
DOIs
Publication statusPublished - 2014 Oct 1

ASJC Scopus subject areas

  • Organic Chemistry

Fingerprint Dive into the research topics of 'N-Allenylnitrone acts as 2-azadiene in the Cu-catalyzed cascade reaction of O-propargylic oximes with azodicarboxylates'. Together they form a unique fingerprint.

Cite this