MX-type single chain complexes with an aromatic in-plane ligand: Incorporation of aromatic interactions for stabilizing the chain structure

Unjila Afrin, Hiroaki Iguchi, Mohammad Rasel Mian, Shinya Takaishi, Hiromichi Yamakawa, Tsubasa Terashige, Tatsuya Miyamoto, Hiroshi Okamoto, Masahiro Yamashita

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

MX-type one-dimensional complexes [PtIV(amp)2Br2][PtII/IV(amp)2Br]2(HSO4)2(SO4)2·13H2O (3) and [PtIV(amp)2Br2][PtII/IV(amp)2Br]2(H2PO4)6·8H2O (4) were synthesized as the first analogue containing only an aromatic in-plane ligand. The Pt-Br chain structures of 3 and 4 are stabilized by both the hydrogen-bond network along the chain and the π-stacking via intercalated Pt(iv) complexes. Structural and spectroscopic studies indicated that both 3 and 4 form the Pt(ii/iv) mixed valence state.

Original languageEnglish
Pages (from-to)7828-7834
Number of pages7
JournalDalton Transactions
Volume48
Issue number22
DOIs
Publication statusPublished - 2019

ASJC Scopus subject areas

  • Inorganic Chemistry

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