Supramolecular cations (SC+) of K+, Rb+, or NH4+(crown ether) were incorporated into the monovalent [Ni(dmit)2]- salts. The K+ and Rb+(DA18-crown-6) units had a planar disk-shaped SC+ structure, while the [NH4+(150-crown-5)2]2 was the barrel type SC+ structure. The [Ni(dmit)2]-arrangement and magnetic properties of these salts depended on the coordination properties in the cation structures.
|Number of pages||6|
|Journal||Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals|
|Publication status||Published - 2000|
|Event||Proceedings of the International Symposium Molecular Design and Funtionalities of Assambled Metals Complexes (AMC'99) - Kyoto, Jpn|
Duration: 1999 Nov 30 → 1999 Dec 2
ASJC Scopus subject areas
- Condensed Matter Physics