M12L24 spheres with endo and Exo coordination sites: Scaffolds for non-covalent functionalization

Kate Harris, Qing Fu Sun, Sota Sato, Makoto Fujita

    Research output: Contribution to journalArticlepeer-review

    56 Citations (Scopus)

    Abstract

    M12L24 spherical complexes incorporating 24 free pyridine rings on their interior or exterior surfaces were synthesized via the self-assembly of tridentate tris(pyridine) ligands with Pd2+ ions. Coordination of secondary metal ions in the interior of the spherical framework was achieved through interactions of 24 Ag+ ions with the free endo pyridine rings.

    Original languageEnglish
    Pages (from-to)12497-12499
    Number of pages3
    JournalJournal of the American Chemical Society
    Volume135
    Issue number34
    DOIs
    Publication statusPublished - 2013 Aug 28

    ASJC Scopus subject areas

    • Catalysis
    • Chemistry(all)
    • Biochemistry
    • Colloid and Surface Chemistry

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