M12L24 spheres with endo and Exo coordination sites: Scaffolds for non-covalent functionalization

Kate Harris; Qing Fu Sun; Sota Sato; Makoto Fujita

doi:10.1021/ja4043609

M₁₂L₂₄ spheres with endo and Exo coordination sites: Scaffolds for non-covalent functionalization

Kate Harris, Qing Fu Sun, Sota Sato, Makoto Fujita

Research output: Contribution to journal › Article › peer-review

56 Citations (Scopus)

Abstract

M₁₂L₂₄ spherical complexes incorporating 24 free pyridine rings on their interior or exterior surfaces were synthesized via the self-assembly of tridentate tris(pyridine) ligands with Pd²⁺ ions. Coordination of secondary metal ions in the interior of the spherical framework was achieved through interactions of 24 Ag⁺ ions with the free endo pyridine rings.

Original language	English
Pages (from-to)	12497-12499
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	135
Issue number	34
DOIs	https://doi.org/10.1021/ja4043609
Publication status	Published - 2013 Aug 28

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja4043609

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abstract = "M12L24 spherical complexes incorporating 24 free pyridine rings on their interior or exterior surfaces were synthesized via the self-assembly of tridentate tris(pyridine) ligands with Pd2+ ions. Coordination of secondary metal ions in the interior of the spherical framework was achieved through interactions of 24 Ag+ ions with the free endo pyridine rings.",

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