Most stable metallic phase of the mixed-valence MMX-chain, Pt 2(dtp)4l (dtp = C2H5CS2), in purely d-electronic conductors based on the transition-metal complex

Kazuya Otsubo, Atsushi Kobayashi, Hiroshi Kitagawa, Masato Hedo, Yoshiya Uwatoko, Hajime Sagayama, Yusuke Wakabayashi, Hiroshi Sawa

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56 Citations (Scopus)

Abstract

The electrical resistivity and X-rayoscillation photograph measurements for an MMX-chain complex, Pt2(dtp)4I (dtp = C2H5CS2-), under high pressure were performed. We observed the most stable metallic phase (TMI = 70 K, under 2.2 GPa) in the 1-D purely d-electronic conductors and pressure-induced metal-insulator transition including the structural phase transition at 3.0 GPa.

Original languageEnglish
Pages (from-to)8140-8141
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number25
DOIs
Publication statusPublished - 2006 Jun 28
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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