MoS2 clusters in the spaces of FAU zeolite

Y. Sakamoto, N. Togashi, O. Terasaki, T. Ohsuna, Y. Okamoto, K. Hiraga

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Molybdenum sulfide clusters were incorporated into FAU zeolite through saturation adsorption of Mo(CO)6 at room temperature followed by a reaction with H2S gas. Using electron microscopy, it was confirmed that the clusters were formed in the supercages of the zeolite without destroying the framework structure. Rietveld analysis of the powder X-ray diffraction pattern suggested that the clusters were formed along the belts which consist of two 4-rings of hexagonal prisms and bridging 4-ring, and are surrounding the supercage.

Original languageEnglish
Pages (from-to)147-150
Number of pages4
JournalMaterials Science and Engineering A
Volume217-218
DOIs
Publication statusPublished - 1996 Oct 30

Keywords

  • Electron microscopy
  • FAU zeolite
  • Molybdenum sulphide

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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