Monolayer Properties of A Perfluoroalkyl Maleate Copolymer on Aqueous Metal ION Subphases

Burm Jong Lee; Hyein Jeong; Jong Hyun Son; Young Soo Kwon; Kazue Kurihara

doi:10.1080/10587259508034009

Monolayer Properties of A Perfluoroalkyl Maleate Copolymer on Aqueous Metal ION Subphases

Burm Jong Lee, Hyein Jeong, Jong Hyun Son, Young Soo Kwon, Kazue Kurihara

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Abstract

Electrostatic interactions between polymers and metal ions at the air-water interface and in resulting LB films were investigated. The polymer was prepared from radical copolymerization of 2-(perfluorooctyl)ethyl monomaleate with triethyleneglycol methyl vinyl ether. The metal ions examined were Na+, Cs\ Mg2+, Fe2+, Al3+, and Fe3+. The surface pressure-area isotherms show that all the monolayers on aqueous metal ions reveal more expanded phases than that on pure water. From the FT-IR (reflection and transmission) spectra, the formation of carboxylate salts and the relative pendent orientation of the polymer in LB film could be estimated. Quantitative analysis of metal ion concentration incorporated into the LB film was carried out by XPS measurement.

Original language	English
Pages (from-to)	311-316
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
Volume	267
Issue number	1
DOIs	https://doi.org/10.1080/10587259508034009
Publication status	Published - 1995 Oct 1
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics

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Monolayer Properties of A Perfluoroalkyl Maleate Copolymer on Aqueous Metal ION Subphases. / Lee, Burm Jong; Jeong, Hyein; Son, Jong Hyun et al.

In: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol. 267, No. 1, 01.10.1995, p. 311-316.

Research output: Contribution to journal › Article › peer-review

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title = "Monolayer Properties of A Perfluoroalkyl Maleate Copolymer on Aqueous Metal ION Subphases",

abstract = "Electrostatic interactions between polymers and metal ions at the air-water interface and in resulting LB films were investigated. The polymer was prepared from radical copolymerization of 2-(perfluorooctyl)ethyl monomaleate with triethyleneglycol methyl vinyl ether. The metal ions examined were Na+, Cs\ Mg2+, Fe2+, Al3+, and Fe3+. The surface pressure-area isotherms show that all the monolayers on aqueous metal ions reveal more expanded phases than that on pure water. From the FT-IR (reflection and transmission) spectra, the formation of carboxylate salts and the relative pendent orientation of the polymer in LB film could be estimated. Quantitative analysis of metal ion concentration incorporated into the LB film was carried out by XPS measurement.",

author = "Lee, {Burm Jong} and Hyein Jeong and Son, {Jong Hyun} and Kwon, {Young Soo} and Kazue Kurihara",

note = "Funding Information: This work was gratefully supported by Korea Science & Engineering Foundation in 1994 (94 1-08OO-019-1 ).",

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AU - Lee, Burm Jong

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AU - Kwon, Young Soo

AU - Kurihara, Kazue

N1 - Funding Information: This work was gratefully supported by Korea Science & Engineering Foundation in 1994 (94 1-08OO-019-1 ).

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N2 - Electrostatic interactions between polymers and metal ions at the air-water interface and in resulting LB films were investigated. The polymer was prepared from radical copolymerization of 2-(perfluorooctyl)ethyl monomaleate with triethyleneglycol methyl vinyl ether. The metal ions examined were Na+, Cs\ Mg2+, Fe2+, Al3+, and Fe3+. The surface pressure-area isotherms show that all the monolayers on aqueous metal ions reveal more expanded phases than that on pure water. From the FT-IR (reflection and transmission) spectra, the formation of carboxylate salts and the relative pendent orientation of the polymer in LB film could be estimated. Quantitative analysis of metal ion concentration incorporated into the LB film was carried out by XPS measurement.

AB - Electrostatic interactions between polymers and metal ions at the air-water interface and in resulting LB films were investigated. The polymer was prepared from radical copolymerization of 2-(perfluorooctyl)ethyl monomaleate with triethyleneglycol methyl vinyl ether. The metal ions examined were Na+, Cs\ Mg2+, Fe2+, Al3+, and Fe3+. The surface pressure-area isotherms show that all the monolayers on aqueous metal ions reveal more expanded phases than that on pure water. From the FT-IR (reflection and transmission) spectra, the formation of carboxylate salts and the relative pendent orientation of the polymer in LB film could be estimated. Quantitative analysis of metal ion concentration incorporated into the LB film was carried out by XPS measurement.

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Monolayer Properties of A Perfluoroalkyl Maleate Copolymer on Aqueous Metal ION Subphases

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