Mono- and penta-addition of enol silyl ethers to [60]fullerene

Eiichi Nakamura, Shinsuke Mouri, Yuki Nakamura, Koji Harano, Hiroyuki Isobe

    Research output: Contribution to journalArticle

    10 Citations (Scopus)

    Abstract

    (Chemical Equation Presented) The reaction of 1-alkoxy-1-siloxyethene with [60]fullerene in 20% DMSO/chlorobenzene at ambient temperature under an oxygen atmosphere gave a penta-addition product, while the reaction of 1-alkoxy-1-siloxyalkenes or 1,2-siloxyalkenes under argon gave monoaddition products. The new method has merits over the previously reported syntheses of these compounds in that the synthesis does not require the use of heavy metals or photolysis conditions, and it can be carried out under simple and mild conditions.

    Original languageEnglish
    Pages (from-to)4923-4926
    Number of pages4
    JournalOrganic letters
    Volume10
    Issue number21
    DOIs
    Publication statusPublished - 2008 Dec 1

    ASJC Scopus subject areas

    • Biochemistry
    • Physical and Theoretical Chemistry
    • Organic Chemistry

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  • Cite this

    Nakamura, E., Mouri, S., Nakamura, Y., Harano, K., & Isobe, H. (2008). Mono- and penta-addition of enol silyl ethers to [60]fullerene. Organic letters, 10(21), 4923-4926. https://doi.org/10.1021/ol8020379