Momentum dependence of π-π* excitations of benzene rings in condensed phases

Hisashi Hayashi, Noboru Watanabe, Yasuo Udagawa, Chi Chang Kao

Research output: Contribution to journalConference article

3 Citations (Scopus)

Abstract

Inelastic X-ray scattering (IXS) spectra for the π-π* excitation of benzene, toluene, polystyrene, and benzene-hexane solutions have been measured at medium momentum transfers (q), 0.35≤q≤1.5 angstroms-1. IXS profiles of these substances closely resemble each other. The π-π* peak of the pure substances shows a negative q-dispersion (approximately 0.5 eV), while diluted benzene does not. For benzene, the loss function and the real (ε1) as well as the imaginary (ε2) parts of the dielectric function were deduced. It is shown that the π-π* excitation in liquids is well-localized and the q-dispersion can be interpreted by changes of the shielding factor ε1222. The properties of the loss function for molecular condensates are discussed.

Original languageEnglish
Pages (from-to)933-937
Number of pages5
JournalJournal of Electron Spectroscopy and Related Phenomena
Volume114-116
DOIs
Publication statusPublished - 2001 Mar
Event8th International Conference on Electronic Spectroscopy and Structure (ICESS-8) - Berkeley, CA, USA
Duration: 2000 Aug 82000 Aug 12

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Radiation
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics
  • Spectroscopy
  • Physical and Theoretical Chemistry

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