Molecular recognition and photopolymerization of nucleobase monolayer containing diacetylene group at the air-water interface

Jin Matsumoto; Kuniharu Ijiro; Masatsugu Shimomura

doi:10.1246/cl.2000.1280

Molecular recognition and photopolymerization of nucleobase monolayer containing diacetylene group at the air-water interface

Jin Matsumoto, Kuniharu Ijiro, Masatsugu Shimomura

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

An amphiphilic diacetylene with thymine (DA-Thy) was newly synthesized. The amphiphile can form solid-state mono-layer and photopolymerize with UV light irradiation at the air-water interface to form blue and red forms of polydiacetylene. Shapes of the crystalline domain of the polydiacetylene mono-layer were changed by base pair formation between DA-Thy and adenine nucleobase dissolved in the water subphase.

Original language	English
Pages (from-to)	1280-1281
Number of pages	2
Journal	Chemistry Letters
Issue number	11
DOIs	https://doi.org/10.1246/cl.2000.1280
Publication status	Published - 2000 Jan 1

ASJC Scopus subject areas

Chemistry(all)

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abstract = "An amphiphilic diacetylene with thymine (DA-Thy) was newly synthesized. The amphiphile can form solid-state mono-layer and photopolymerize with UV light irradiation at the air-water interface to form blue and red forms of polydiacetylene. Shapes of the crystalline domain of the polydiacetylene mono-layer were changed by base pair formation between DA-Thy and adenine nucleobase dissolved in the water subphase.",

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