Molecular design of organic ferrimagnets

D. Shiomi, M. Nishizawa, K. Kamiyama, S. Hase, T. Kanaya, K. Sato, T. Takui

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)

Abstract

Two kinds of molecular design for genuinely organic molecule-based ferrimagnetics are reported. (I) The coulombic interaction between an anion and a cation is utilised for co-crystallizing organic radical molecules with different spin quantum numbers. This is referred to "organic salt ferrimagnetics". A phenol derivative of nitronyl nitroxide π-biradical with S=I has been synthesised as an anionic component of the salt and the electronic spin structure characterized, (II) The phenolic π-biradical with S=I and a carboxyl-substituted π-radicals with S=1/2 have been esterified to give model compounds for "single-component ferrimagnetics". Potentialities of the model compounds as building blocks of molecule-based ferrimagnetics have been examined by susceptibility and ESR measurements.

Original languageEnglish
Pages (from-to)1810-1811
Number of pages2
JournalSynthetic Metals
Volume121
Issue number1-3
DOIs
Publication statusPublished - 2001 Mar 15
Externally publishedYes

Keywords

  • Electron spin resonance
  • Magnetic measurements

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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