MnIII salen-type single-molecule magnet fixed in a two-dimensional network

Chihiro Kachi-Terajima, Elina Mori, Tasuku Eiba, Toshiaki Saito, Chikahide Kanadani, Takafumi Kitazawa, Hitoshi Miyasaka

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

A two-dimensional network compound, [{Mn(saltmen)}4{Co(CN)6}](ClO4)·9H20 (2) (saltmen2- = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminate)), was synthesized. Magnetic measurements characterized the [Mn2(saltmen)2]2+ subunit as a single-molecule magnet with an ST = 4 spin ground state, indicating that the MnIII dimer is magnetically isolated not only by the diamagnetic [Co(CN)6]3- unit but also by the space between the layers.

Original languageEnglish
Pages (from-to)94-95
Number of pages2
JournalChemistry Letters
Volume39
Issue number2
DOIs
Publication statusPublished - 2010

ASJC Scopus subject areas

  • Chemistry(all)

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