Mixed-valence states in MMX-chains complex, Pt2(dta)4I

Hiroshi Kitagawa, Noriaki Onodera, Jeung Sun Ahn, Tadaoki Mitani, Misa Kim, Yoshiki Ozawa, Koshiro Toriumi, Kazutomo Yasui, Toshio Manabe, Masahiro Yamashita

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26 Citations (Scopus)

Abstract

Physical and structural properties of the MMX-type halogen-bridged mixed-valence complex, Pt2(dta)4I (dta = CH3CS2) were investigated. This complex exhibits metallic conduction above room temperature, which is the first observation in halogen-bridged 1-D transition-metal complexes. Below 300 K, the metal-semiconductor transition was observed. The mixed-valence state of this compound is discussed.

Original languageEnglish
Pages (from-to)311-316
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume285-286
DOIs
Publication statusPublished - 1996 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Condensed Matter Physics

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    Kitagawa, H., Onodera, N., Ahn, J. S., Mitani, T., Kim, M., Ozawa, Y., Toriumi, K., Yasui, K., Manabe, T., & Yamashita, M. (1996). Mixed-valence states in MMX-chains complex, Pt2(dta)4I. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 285-286, 311-316. https://doi.org/10.1080/10587259608030818