Mixed conductivity and electrode properties of Mn-doped Bi-Sr-Fe-based perovskite-type oxides

Doohyun Baek, Atsunori Kamegawa, Hitoshi Takamura

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

The Fe-site of Bi0.7Sr0.3FeO3 - δ (BSF) was doped with manganese to determine any changes in the charged defects and understand how this change affects the electrode properties of this material. The electrical conductivity and oxygen permeability results suggest that Mn-doping effectively improves the electronic compensation of BSF, which is energetically favored by ionic compensation. In terms of electrode properties, 50 mol% Mn-doped BSF (BSFM55) showed more than one order of magnitude greater electrode resistance than BSF, suggesting that kinetics related to ionic defects plays a more important role than electronic defects in determining the properties of Bi-Sr-Fe based perovskite oxides.

Original languageEnglish
Pages (from-to)211-216
Number of pages6
JournalSolid State Ionics
Volume253
DOIs
Publication statusPublished - 2013 Nov 11

Keywords

  • Bi-Sr-Fe-based perovskite-type oxide
  • Mixed ionic and electronic conductor
  • Mn-doping effect
  • Oxygen permeable membrane
  • SOFC cathode

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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