Microspheric Na2Ti3O7 consisting of tiny nanotubes: An anode material for sodium-ion batteries with ultrafast charge-discharge rates

Wei Wang, Chengjun Yu, Zheshuai Lin, Jungang Hou, Hongmin Zhu, Shuqiang Jiao

Research output: Contribution to journalArticlepeer-review

139 Citations (Scopus)

Abstract

Conventionally, rechargeable batteries with a fast charge-discharge rate, while being able to be implemented in large-scale applications with low prices, are critical for new energy storage systems. In this work, first-principles simulations were employed to theoretically investigate the insertion of sodium into the Na2Ti3O7 structure. The result discovered that the theoretical capacity of Na2Ti3O 7 was 311 mA h g-1. Furthermore, a microspheric Na 2Ti3O7 material consisting of tiny nanotubes of ca. 8 nm in outside diameter and a few hundred nanometers in length has been synthesized. The galvanostatic charge-discharge measurements, using the as-prepared Na2Ti3O7 nanotubes as a working electrode with a voltage range of 0.01-2.5 V vs. Na+/Na, disclosed that a high capacity was maintained even under an ultrafast charge-discharge rate. At a current density of 354 mA g-1, the discharge capacity was maintained at 108 mA h g-1 over 100 cycles. Even at a very large current density of 3540 mA g-1, the discharge capacity was still 85 mA h g-1. HRTEM analysis and electrochemical tests proved that sodium ions could not only intercalate into the Na2Ti3O 7 crystal, but could also be stored in the intracavity of the nanotubes. All of the results disclose that the as-prepared Na 2Ti3O7 nanotubes are able to be used as anode materials in large-scale applications for rechargeable sodium-ion batteries at low cost while maintaining excellent performance.

Original languageEnglish
Pages (from-to)594-599
Number of pages6
JournalNanoscale
Volume5
Issue number2
DOIs
Publication statusPublished - 2013 Jan 21
Externally publishedYes

ASJC Scopus subject areas

  • Materials Science(all)

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