Microporous structures having phenylene fin: Significance of substituent groups for rotational linkers in coordination polymers

Ryotaro Matsuda, Wataru Kosaka, Ryo Kitaura, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Microporous coordination polymers having various shaped apertures were synthesized and crystallographically characterized using substituted terephthalate ligands. The substituents exert a notable influence on the channel size and shape depending on the orientations and disordering of the phenylene units such as a fin. This is a new aspect of porous coordination polymers, which would provide important information for a precise design of the micropore.

Original languageEnglish
Pages (from-to)83-90
Number of pages8
JournalMicroporous and Mesoporous Materials
Volume189
DOIs
Publication statusPublished - 2014 May 1

Keywords

  • Adsorption
  • Metal-organic frameworks
  • Micropore
  • Porous coordination polymers

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials

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