Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst

Shota Teramae; Akane Kito; Tomoteru Shingaki; Yu Hamaguchi; Yuuki Yano; Takamori Nakayama; Yuko Kobayashi; Nobuki Kato; Naoki Umezawa; Yosuke Hisamatsu; Tetsuo Nagano; Tsunehiko Higuchi

doi:10.1039/c9cc03041g

Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst

Shota Teramae, Akane Kito, Tomoteru Shingaki, Yu Hamaguchi, Yuuki Yano, Takamori Nakayama, Yuko Kobayashi, Nobuki Kato, Naoki Umezawa, Yosuke Hisamatsu, Tetsuo Nagano, Tsunehiko Higuchi

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Regioselective C-H oxidation of aliphatic molecules with synthetic catalysts is challenging. We incorporated substrate-recognition sites into a ruthenium porphyrin-heteroaromatic N-oxide catalytic system in order to characterise its regioselectivity for the oxidation of alkanes. This substrate-recognition catalytic reaction exhibits high regioselectivity and high reaction efficiency.

Original language	English
Pages (from-to)	8378-8381
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	58
DOIs	https://doi.org/10.1039/c9cc03041g
Publication status	Published - 2019
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c9cc03041g

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title = "Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst",

abstract = "Regioselective C-H oxidation of aliphatic molecules with synthetic catalysts is challenging. We incorporated substrate-recognition sites into a ruthenium porphyrin-heteroaromatic N-oxide catalytic system in order to characterise its regioselectivity for the oxidation of alkanes. This substrate-recognition catalytic reaction exhibits high regioselectivity and high reaction efficiency.",

author = "Shota Teramae and Akane Kito and Tomoteru Shingaki and Yu Hamaguchi and Yuuki Yano and Takamori Nakayama and Yuko Kobayashi and Nobuki Kato and Naoki Umezawa and Yosuke Hisamatsu and Tetsuo Nagano and Tsunehiko Higuchi",

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doi = "10.1039/c9cc03041g",

language = "English",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst

AU - Teramae, Shota

AU - Kito, Akane

AU - Shingaki, Tomoteru

AU - Hamaguchi, Yu

AU - Yano, Yuuki

AU - Nakayama, Takamori

AU - Kobayashi, Yuko

AU - Kato, Nobuki

AU - Umezawa, Naoki

AU - Hisamatsu, Yosuke

AU - Nagano, Tetsuo

AU - Higuchi, Tsunehiko

PY - 2019

Y1 - 2019

N2 - Regioselective C-H oxidation of aliphatic molecules with synthetic catalysts is challenging. We incorporated substrate-recognition sites into a ruthenium porphyrin-heteroaromatic N-oxide catalytic system in order to characterise its regioselectivity for the oxidation of alkanes. This substrate-recognition catalytic reaction exhibits high regioselectivity and high reaction efficiency.

AB - Regioselective C-H oxidation of aliphatic molecules with synthetic catalysts is challenging. We incorporated substrate-recognition sites into a ruthenium porphyrin-heteroaromatic N-oxide catalytic system in order to characterise its regioselectivity for the oxidation of alkanes. This substrate-recognition catalytic reaction exhibits high regioselectivity and high reaction efficiency.

UR - http://www.scopus.com/inward/record.url?scp=85069190744&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85069190744&partnerID=8YFLogxK

U2 - 10.1039/c9cc03041g

DO - 10.1039/c9cc03041g

M3 - Article

C2 - 31233056

AN - SCOPUS:85069190744

SN - 1359-7345

VL - 55

SP - 8378

EP - 8381

JO - Chemical Communications

JF - Chemical Communications

IS - 58

ER -

Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst

Abstract

ASJC Scopus subject areas

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