Abstract
Trains and boats and planes: The thermolysis of a tri ruthenium complex having H3-pentylidyne and μ3-pentyne ligands on each face of the tri metallic plane exclusively afforded the μ3- ethylidyne-nroctyne complex. In this reaction, a C3 fragment migrated from one face of the Ru3 planeto the other. This corresponds to the selective redistribution of two C5 molecules into C2 and C8 molecules. (Figure Presented)
Original language | English |
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Pages (from-to) | 5898-5901 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 49 |
Issue number | 34 |
DOIs | |
Publication status | Published - 2010 Aug 9 |
Externally published | Yes |
Keywords
- C-C activation
- Cluster compounds
- Metallacycles
- Metathesis
- Ruthenium
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)