Metathesis reaction of hydrocarbyl ligands across the triruthenium plane

Atsushi Tahara; Mana Kajigaya; Makoto Moriya; Toshiro Takao; Hiroharu Suzuki

doi:10.1002/anie.201002235

Metathesis reaction of hydrocarbyl ligands across the triruthenium plane

Atsushi Tahara, Mana Kajigaya, Makoto Moriya, Toshiro Takao, Hiroharu Suzuki

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Trains and boats and planes: The thermolysis of a tri ruthenium complex having H₃-pentylidyne and μ₃-pentyne ligands on each face of the tri metallic plane exclusively afforded the μ₃- ethylidyne-nroctyne complex. In this reaction, a C₃ fragment migrated from one face of the Ru₃ planeto the other. This corresponds to the selective redistribution of two C₅ molecules into C₂ and C₈ molecules. (Figure Presented)

Original language	English
Pages (from-to)	5898-5901
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	34
DOIs	https://doi.org/10.1002/anie.201002235
Publication status	Published - 2010 Aug 9
Externally published	Yes

Keywords

C-C activation
Cluster compounds
Metallacycles
Metathesis
Ruthenium

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.201002235

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title = "Metathesis reaction of hydrocarbyl ligands across the triruthenium plane",

abstract = "Trains and boats and planes: The thermolysis of a tri ruthenium complex having H3-pentylidyne and μ3-pentyne ligands on each face of the tri metallic plane exclusively afforded the μ3- ethylidyne-nroctyne complex. In this reaction, a C3 fragment migrated from one face of the Ru3 planeto the other. This corresponds to the selective redistribution of two C5 molecules into C2 and C8 molecules. (Figure Presented)",

keywords = "C-C activation, Cluster compounds, Metallacycles, Metathesis, Ruthenium",

author = "Atsushi Tahara and Mana Kajigaya and Makoto Moriya and Toshiro Takao and Hiroharu Suzuki",

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language = "English",

volume = "49",

pages = "5898--5901",

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T1 - Metathesis reaction of hydrocarbyl ligands across the triruthenium plane

AU - Tahara, Atsushi

AU - Kajigaya, Mana

AU - Moriya, Makoto

AU - Takao, Toshiro

AU - Suzuki, Hiroharu

PY - 2010/8/9

Y1 - 2010/8/9

N2 - Trains and boats and planes: The thermolysis of a tri ruthenium complex having H3-pentylidyne and μ3-pentyne ligands on each face of the tri metallic plane exclusively afforded the μ3- ethylidyne-nroctyne complex. In this reaction, a C3 fragment migrated from one face of the Ru3 planeto the other. This corresponds to the selective redistribution of two C5 molecules into C2 and C8 molecules. (Figure Presented)

AB - Trains and boats and planes: The thermolysis of a tri ruthenium complex having H3-pentylidyne and μ3-pentyne ligands on each face of the tri metallic plane exclusively afforded the μ3- ethylidyne-nroctyne complex. In this reaction, a C3 fragment migrated from one face of the Ru3 planeto the other. This corresponds to the selective redistribution of two C5 molecules into C2 and C8 molecules. (Figure Presented)

KW - C-C activation

KW - Cluster compounds

KW - Metallacycles

KW - Metathesis

KW - Ruthenium

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 34

ER -

Metathesis reaction of hydrocarbyl ligands across the triruthenium plane

Abstract

Keywords

ASJC Scopus subject areas

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