Metastable sorption state of a metal-organic porous material determined by in situ synchrotron powder diffraction

Yoshiki Kubota, Masaki Takata, Ryotaro Matsuda, Ryo Kitaura, Susumu Kitagawa, Tatsuo C. Kobayashi

Research output: Contribution to journalArticlepeer-review

92 Citations (Scopus)

Abstract

(Figure Presented) Guest-responsive framework: Gas adsorption into a metal-organic porous material was studies in situ. Structure analysis of empty phase I, intermediate phase M as a metastable state of gas adsorption, and saturated phase S showed rearrangement of guest molecules and framework transformation in response to guest size, shape, and amount. The picture shows these changes for the superimposed phases M and S.

Original languageEnglish
Pages (from-to)4932-4936
Number of pages5
JournalAngewandte Chemie - International Edition
Volume45
Issue number30
DOIs
Publication statusPublished - 2006 Jul 24
Externally publishedYes

Keywords

  • Adsorption
  • Metal-organic frameworks
  • Microporous materials
  • Structure elucidation
  • X-ray diffraction

ASJC Scopus subject areas

  • Chemistry(all)

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