Abstract
A series of new scandium complexes supported by the phthalocyanine (Pc) ligand have been prepared and structurally characterized. Reaction of ScCl3 with phthalonitrile affords a mixture of PcScCl (1) and unreacted ScCl3, which upon addition of LiCH(SiMe3)2 yields THF-soluble PcSc(μ-Cl2)Li(THF)2 (2). Metathesis with NaCp or LiCp∗ generates PcSc(η5-C5H5) and PcSc(η5-C5Me5), respectively, which represent the first examples of η5-Cp metal phthalocyanines where the Cp fragment sandwiches the metal centre.
Original language | English |
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Pages (from-to) | 5986-5989 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 51 |
Issue number | 27 |
DOIs | |
Publication status | Published - 2015 Apr 7 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry