Metallic properties of 1:1 charge-transfer salt DMTSA-BF4

K. Yakushi, J. Dong, J. Ouyang, K. Takimiya, T. Otsubo, H. Tajima

Research output: Contribution to journalConference articlepeer-review

Abstract

Although DMTSA-BF4 has a half-filled band, the electrical resistivity and thermopower shows that this compound is metallic and undergoes metal-insulator transition at ca. 150 K. By polarized reflection spectrum, this compound is characterized as a pseudo-one-dimensional metal with a bandwidth of 0.8 eV. The band calculation suggests a one-dimensional nature of the Fermi surface. The optical transition from the bottom of the conduction band to the top of the folded conduction band is observed in the infrared region. The temperature dependence of the reflection spectrum suggests a strong fluctuation of the lattice dimerization above the phase transition temperature.

Original languageEnglish
Pages (from-to)2208-2209
Number of pages2
JournalSynthetic Metals
Volume103
Issue number1-3
DOIs
Publication statusPublished - 1999 Jun 24
Externally publishedYes
EventProceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier
Duration: 1998 Jul 121998 Jul 18

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Metallic properties of 1:1 charge-transfer salt DMTSA-BF<sub>4</sub>'. Together they form a unique fingerprint.

Cite this