Metal-substituted disilynes with linear forms

Masae Takahashi, Yoshiyuki Kawazoe

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

The present systematic survey of linear disilynes ESi≡SiE with various metal elements E by ab initio and density functional theory calculations has shown that magnesium is highly suited to stabilize the linear conformation of the Si≡Si bond. A synthetically accessible model compound using the magnesium complex of a core-modified porphyrin as a substituent has been designed.

Original languageEnglish
Pages (from-to)4829-4832
Number of pages4
JournalOrganometallics
Volume27
Issue number19
DOIs
Publication statusPublished - 2008 Oct 13

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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