Metal-silicate partitioning and constraints on core composition and oxygen fugacity during Earth accretion

Alexandre Corgne, Shantanu Keshav, Bernard J. Wood, William Francis Mc Donough, Yingwei Fei

Research output: Contribution to journalArticlepeer-review

130 Citations (Scopus)

Abstract

We present the results of new partitioning experiments between metal and silicate melts for a series of elements normally regarded as refractory lithophile and moderately siderophile and volatile. These include Si, Ti, Ni, Cr, Mn, Ga, Nb, Ta, Cu and Zn. Our new data obtained at 3.6 and 7.7 GPa and between 2123 and 2473 K are combined with literature data to parameterize the individual effects of oxygen fugacity, temperature, pressure and composition on partitioning. We find that Ni, Cu and Zn become less siderophile with increasing temperature. In contrast, Mn, Cr, Si, Ta, Nb, Ga and Ti become more siderophile with increasing temperature, with the highly charged cations (Nb, Ta, Si and Ti) being the most sensitive to variations of temperature. We also find that Ni, Cr, Nb, Ta and Ga become less siderophile with increasing pressure, while Mn becomes more siderophile with increasing pressure. Pressure effects on the partitioning of Si, Ti, Cu and Zn appear to be negligible, as are the effects of silicate melt composition on the partitioning of divalent cations. From the derived parameterization, we predict that the silicate Earth abundances of the elements mentioned above are best explained if core formation in a magma ocean took place under increasing conditions of oxygen fugacity, starting from moderately reduced conditions and finishing at the current mantle-core equilibrium value.

Original languageEnglish
Pages (from-to)574-589
Number of pages16
JournalGeochimica et Cosmochimica Acta
Volume72
Issue number2
DOIs
Publication statusPublished - 2008 Jan 15
Externally publishedYes

ASJC Scopus subject areas

  • Geochemistry and Petrology

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