Metal-Organic Nanotube with Helical and Propeller-Chiral Motifs Composed of a C10-Symmetric Double-Decker Nanoring

Hiroshi Yamagishi, Takahiro Fukino, Daisuke Hashizume, Tadashi Mori, Yoshihisa Inoue, Takaaki Hikima, Masaki Takata, Takuzo Aida

Research output: Contribution to journalArticlepeer-review

28 Citations (Scopus)

Abstract

Coassembly of an achiral ferrocene-cored tetratopic pyridyl ligand (FcL) with AgBF4 in CH2Cl2/MeCN (7:3 v/v) containing chiral Bu4N+ (+)- or (-)-menthylsulfate (MS∗-) results in the formation of an "optically active" metal-organic nanotube (FcNT) composed of a C10-symmetric double-decker nanoring featuring 10 FcL units and 20 Ag+ ions. The circular dichroism spectrum of FcNT along with its 2D X-ray diffraction (2D XRD) pattern indicates that the constituent metal-organic nanorings in FcNT stack one-handed helically on top of each other. A crystal structure of the dimeric double-decker model complex (Ag2(FcL′)2) from a ditopic ferrocene ligand (FcL′) and AgBF4 allowed for confirming the binding of MS∗- onto the Ag+ center of the complex. The results of detailed spectroscopic studies indicate that in its double-decker aromatic arrays, FcNT possibly possesses propeller-chiral twists in addition to the helically chiral structure, where the former is considerably more dynamic than the latter. Notably, both chiral structural motifs responded nonlinearly to an enantiomeric excess of MS∗- (majority rule) though with no stereochemical influence on one another.

Original languageEnglish
Pages (from-to)7628-7631
Number of pages4
JournalJournal of the American Chemical Society
Volume137
Issue number24
DOIs
Publication statusPublished - 2015 Jun 24
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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