Metal-organic frameworks with rare topologies: Lonsdaleite-type metal formates and their magnetic properties

Hyunuk Kim, Yinyong Sun, Yonghwi Kim, Takashi Kajiwara, Masahiro Yamashita, Kimoon Kim

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Single-crystal X-ray analysis revealed that isomorphous metal formates [M6(HCOO)12]·DEF (M = Mg2+, Fe 2+, Co2+, Zn2+) have a framework with the lonsdaleite net, which is one of the rare topologies in metal-organic frameworks; iron and cobalt formates with metal sites bridged by single atoms showed dominant ferromagnetic and antiferromagnetic interactions, respectively.

Original languageEnglish
Pages (from-to)2197-2200
Number of pages4
JournalCrystEngComm
Volume13
Issue number7
DOIs
Publication statusPublished - 2011 Apr 7

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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