Metal-catalyzed stereoselective and protecting-group-free synthesis of 1,2-cis-glycosides using 4,6-dimethoxy-1,3,5-triazin-2-yl glycosides as glycosyl donors

Tomonari Tanaka, Naoya Kikuta, Yoshiharu Kimura, Shin Ichiro Shoda

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

4,6-Dimethoxy-1,3,5-triazin-2-yl glycosides, glycosyl donors prepared in one step from free saccharides without protection of the hydroxy groups, were stereoselectively and equivalently converted to the corresponding 1,2-cis-glycosides by using a catalytic amount of metal catalyst. This reaction was successfully applied not only to monosaccharides, but also to di- and oligosaccharides.

Original languageEnglish
Pages (from-to)846-848
Number of pages3
JournalChemistry Letters
Volume44
Issue number6
DOIs
Publication statusPublished - 2015 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)

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