Me2s-induced highly selective reduction of aldehydes in the presence of ketones involving aldehyde-selective rate enhancement: A triruthenium cluster-catalyzed hydrosilylation

Shohei Yumino; Toru Hashimoto; Atsushi Tahara; Hideo Nagashima

doi:10.1246/cl.140731

Me₂s-induced highly selective reduction of aldehydes in the presence of ketones involving aldehyde-selective rate enhancement: A triruthenium cluster-catalyzed hydrosilylation

Shohei Yumino, Toru Hashimoto, Atsushi Tahara, Hideo Nagashima

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Addition of appropriate amounts of Me₂S unusually accelerated the hydrosilylation of aldehydes catalyzed by [Ru₃(CO)₇(Acy)] (1, Acy: μ₃-η²,η³,η⁵-acenaphthylene). The reduction of ketones was completely suppressed under the reaction conditions. The highly selective reduction of aldehydes in the presence of ketones was achieved via a nonconventional mechanism.

Original language	English
Pages (from-to)	1829-1831
Number of pages	3
Journal	Chemistry Letters
Volume	43
Issue number	12
DOIs	https://doi.org/10.1246/cl.140731
Publication status	Published - 2014
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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Me₂s-induced highly selective reduction of aldehydes in the presence of ketones involving aldehyde-selective rate enhancement : A triruthenium cluster-catalyzed hydrosilylation. / Yumino, Shohei; Hashimoto, Toru; Tahara, Atsushi; Nagashima, Hideo.

In: Chemistry Letters, Vol. 43, No. 12, 2014, p. 1829-1831.

Research output: Contribution to journal › Article › peer-review

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abstract = "Addition of appropriate amounts of Me2S unusually accelerated the hydrosilylation of aldehydes catalyzed by [Ru3(CO)7(Acy)] (1, Acy: μ3-η2,η3,η5-acenaphthylene). The reduction of ketones was completely suppressed under the reaction conditions. The highly selective reduction of aldehydes in the presence of ketones was achieved via a nonconventional mechanism.",

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AU - Tahara, Atsushi

AU - Nagashima, Hideo

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Me₂s-induced highly selective reduction of aldehydes in the presence of ketones involving aldehyde-selective rate enhancement: A triruthenium cluster-catalyzed hydrosilylation

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