Meso-trifluoromethyl-substituted subporphyrin from ring-splitting reaction of meso-trifluoromethyl-substituted [32]Heptaphyrin(1.1.1.1.1.1.1)

Ryu Sakamoto; Shohei Saito; Soji Shimizu; Yasuhide Inokuma; Naoki Aratani; Atsuhiro Osuka

doi:10.1246/cl.2010.439

Meso-trifluoromethyl-substituted subporphyrin from ring-splitting reaction of meso-trifluoromethyl-substituted [32]Heptaphyrin(1.1.1.1.1.1.1)

Ryu Sakamoto, Shohei Saito, Soji Shimizu, Yasuhide Inokuma, Naoki Aratani, Atsuhiro Osuka

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

meso-Trifluoromethyl-substituted subporphyrin was obtained through an extrusion reaction from meso-trifluoromethyl-substituted heptaphyrin( 1.1.1.1.1.1.1) upon combined metallation of Cu(II) and B(III) ions. The subporphyrin exhibited the most blue-shifted Soret-like absorption band among those ever prepared.

Original language	English
Pages (from-to)	439-441
Number of pages	3
Journal	Chemistry Letters
Volume	39
Issue number	5
DOIs	https://doi.org/10.1246/cl.2010.439
Publication status	Published - 2010 May 3

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2010.439

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Meso-trifluoromethyl-substituted subporphyrin from ring-splitting reaction of meso-trifluoromethyl-substituted [32]Heptaphyrin(1.1.1.1.1.1.1). / Sakamoto, Ryu; Saito, Shohei; Shimizu, Soji; Inokuma, Yasuhide; Aratani, Naoki; Osuka, Atsuhiro.

In: Chemistry Letters, Vol. 39, No. 5, 03.05.2010, p. 439-441.

Research output: Contribution to journal › Article › peer-review

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AU - Saito, Shohei

AU - Shimizu, Soji

AU - Inokuma, Yasuhide

AU - Aratani, Naoki

AU - Osuka, Atsuhiro

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Meso-trifluoromethyl-substituted subporphyrin from ring-splitting reaction of meso-trifluoromethyl-substituted [32]Heptaphyrin(1.1.1.1.1.1.1)

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