meso-Aryl subporphyrins

Nagao Kobayashi; Yuichi Takeuchi; Atsushi Matsuda

doi:10.1002/anie.200603520

meso-Aryl subporphyrins

Nagao Kobayashi, Yuichi Takeuchi, Atsushi Matsuda

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

135 Citations (Scopus)

Abstract

(Figure Presented) Ring-contracted porphyrins: meso-Aryl subporphyrins were synthesized by using a method in which tripyrrolylborane acts as a template for the Adler method. This study demonstrates that, although the subporphyrins retain porphyrinic properties, ring contraction has a significant impact on the electronic structure. The picture shows the DFT-optimized structure of the meso-phenyl subporphyrin (B yellow, N blue, O red, C green, H white).

Original language	English
Pages (from-to)	758-760
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	5
DOIs	https://doi.org/10.1002/anie.200603520
Publication status	Published - 2007 Jan 31

Keywords

Aromaticity
Boron
Macrocycles
Porphyrinoids
Template synthesis

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200603520

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title = "meso-Aryl subporphyrins",

abstract = "(Figure Presented) Ring-contracted porphyrins: meso-Aryl subporphyrins were synthesized by using a method in which tripyrrolylborane acts as a template for the Adler method. This study demonstrates that, although the subporphyrins retain porphyrinic properties, ring contraction has a significant impact on the electronic structure. The picture shows the DFT-optimized structure of the meso-phenyl subporphyrin (B yellow, N blue, O red, C green, H white).",

keywords = "Aromaticity, Boron, Macrocycles, Porphyrinoids, Template synthesis",

author = "Nagao Kobayashi and Yuichi Takeuchi and Atsushi Matsuda",

year = "2007",

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language = "English",

volume = "46",

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T1 - meso-Aryl subporphyrins

AU - Kobayashi, Nagao

AU - Takeuchi, Yuichi

AU - Matsuda, Atsushi

PY - 2007/1/31

Y1 - 2007/1/31

N2 - (Figure Presented) Ring-contracted porphyrins: meso-Aryl subporphyrins were synthesized by using a method in which tripyrrolylborane acts as a template for the Adler method. This study demonstrates that, although the subporphyrins retain porphyrinic properties, ring contraction has a significant impact on the electronic structure. The picture shows the DFT-optimized structure of the meso-phenyl subporphyrin (B yellow, N blue, O red, C green, H white).

AB - (Figure Presented) Ring-contracted porphyrins: meso-Aryl subporphyrins were synthesized by using a method in which tripyrrolylborane acts as a template for the Adler method. This study demonstrates that, although the subporphyrins retain porphyrinic properties, ring contraction has a significant impact on the electronic structure. The picture shows the DFT-optimized structure of the meso-phenyl subporphyrin (B yellow, N blue, O red, C green, H white).

KW - Aromaticity

KW - Boron

KW - Macrocycles

KW - Porphyrinoids

KW - Template synthesis

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 5

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meso-Aryl subporphyrins

Abstract

Keywords

ASJC Scopus subject areas

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