meso-Aryl subporphyrins

Nagao Kobayashi; Yuichi Takeuchi; Atsushi Matsuda

doi:10.1002/anie.200603520

meso-Aryl subporphyrins

Nagao Kobayashi, Yuichi Takeuchi, Atsushi Matsuda

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

148 Citations (Scopus)

Abstract

(Figure Presented) Ring-contracted porphyrins: meso-Aryl subporphyrins were synthesized by using a method in which tripyrrolylborane acts as a template for the Adler method. This study demonstrates that, although the subporphyrins retain porphyrinic properties, ring contraction has a significant impact on the electronic structure. The picture shows the DFT-optimized structure of the meso-phenyl subporphyrin (B yellow, N blue, O red, C green, H white).

Original language	English
Pages (from-to)	758-760
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	5
DOIs	https://doi.org/10.1002/anie.200603520
Publication status	Published - 2007 Jan 31

Keywords

Aromaticity
Boron
Macrocycles
Porphyrinoids
Template synthesis

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.200603520

Cite this

@article{59a7360349a540a48d707d373aea79d9,

title = "meso-Aryl subporphyrins",

abstract = "(Figure Presented) Ring-contracted porphyrins: meso-Aryl subporphyrins were synthesized by using a method in which tripyrrolylborane acts as a template for the Adler method. This study demonstrates that, although the subporphyrins retain porphyrinic properties, ring contraction has a significant impact on the electronic structure. The picture shows the DFT-optimized structure of the meso-phenyl subporphyrin (B yellow, N blue, O red, C green, H white).",

keywords = "Aromaticity, Boron, Macrocycles, Porphyrinoids, Template synthesis",

author = "Nagao Kobayashi and Yuichi Takeuchi and Atsushi Matsuda",

year = "2007",

month = jan,

day = "31",

doi = "10.1002/anie.200603520",

language = "English",

volume = "46",

pages = "758--760",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "5",

}

TY - JOUR

T1 - meso-Aryl subporphyrins

AU - Kobayashi, Nagao

AU - Takeuchi, Yuichi

AU - Matsuda, Atsushi

PY - 2007/1/31

Y1 - 2007/1/31

N2 - (Figure Presented) Ring-contracted porphyrins: meso-Aryl subporphyrins were synthesized by using a method in which tripyrrolylborane acts as a template for the Adler method. This study demonstrates that, although the subporphyrins retain porphyrinic properties, ring contraction has a significant impact on the electronic structure. The picture shows the DFT-optimized structure of the meso-phenyl subporphyrin (B yellow, N blue, O red, C green, H white).

AB - (Figure Presented) Ring-contracted porphyrins: meso-Aryl subporphyrins were synthesized by using a method in which tripyrrolylborane acts as a template for the Adler method. This study demonstrates that, although the subporphyrins retain porphyrinic properties, ring contraction has a significant impact on the electronic structure. The picture shows the DFT-optimized structure of the meso-phenyl subporphyrin (B yellow, N blue, O red, C green, H white).

KW - Aromaticity

KW - Boron

KW - Macrocycles

KW - Porphyrinoids

KW - Template synthesis

UR - http://www.scopus.com/inward/record.url?scp=33846493042&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33846493042&partnerID=8YFLogxK

U2 - 10.1002/anie.200603520

DO - 10.1002/anie.200603520

M3 - Article

C2 - 17163570

AN - SCOPUS:33846493042

VL - 46

SP - 758

EP - 760

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 5

ER -

meso-Aryl subporphyrins

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this