meso-aryl expanded porphyrins: Synthesis, structures, and coordination chemistry

Soji Shimizu, Atsuhiro Osuka

Research output: Contribution to journalShort survey

16 Citations (Scopus)

Abstract

meso-aryl expanded porphyrins, that can be regarded as real homologues of meso-tetraaryl porphyrins, were prepared by our synthetic protocol under the modified Rothemund-Lindsey conditions. This new class of molecules exhibits interesting spectral, electrochemical, and coordination properties. These promising features are emphasized, with a particular attention on the annulenic properties.

Original languageEnglish
Pages (from-to)175-181
Number of pages7
JournalJournal of Porphyrins and Phthalocyanines
Volume8
Issue number1-3
Publication statusPublished - 2004 Jan 1

Keywords

  • Aromaticity
  • Expanded porphyrins
  • Porphyrin

ASJC Scopus subject areas

  • Chemistry(all)

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