Mechanistic and synthetic aspects of hydroboration with a simple atropisomeric ligand prepared from 1-(1′-(isoquinolyl)-2-naphthol

Andrei Korostylev, Ilya Gridnev, John M. Brown

Research output: Contribution to journalArticlepeer-review

23 Citations (Scopus)

Abstract

A novel triarylphosphite ligand has been prepared directly from both enantiomers of BINOL and a single enantiomer of 1′ -(isoquinolyl)-2-naphthol. In one of the two cases cationic Rh complex proved to be reasonably effective in the asymmetric hydroboration of electron-poor styrenes. It was possible to identify binuclear reactive intermediates when the hydroboration pre-catalyst was examined in the presence of catecholborane at low temperatures.

Original languageEnglish
Pages (from-to)329-334
Number of pages6
JournalJournal of Organometallic Chemistry
Volume680
Issue number1-2
DOIs
Publication statusPublished - 2003 Aug 29
Externally publishedYes

Keywords

  • Catecholborane
  • Enantiomer
  • Styrene

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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