The mass spectrometric fragmentation of 1-(benzyloxycarbonyl)amino-2-alkyl/ cycloalkyl thioacetates has been studied with the aid of mass-analysed ion kinetic energy spectrometry under electron impact ionization. All compounds show a tendency to eliminate a ketene, thioacetic acid, and benzyl carbamate molecule, or an acetyl and benzyloxy radicals. A thioester pyrolysis-type rearrangement under electron impact ionizations was observed.
|Number of pages||4|
|Journal||Chinese Chemical Letters|
|Publication status||Published - 2006 Aug 1|
- Electron impact ionization
- Mass spectrometry
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