Manganese(III,IV) and manganese(III) oxide clusters trapped by copper(II) complexes

Satoshi Yamashita, Takuya Shiga, Masashi Kurashina, Masayuki Nihei, Hiroyuki Nojiri, Hiroshi Sawa, Toru Kakiuchi, Hiroki Oshio

Research output: Contribution to journalArticlepeer-review

30 Citations (Scopus)

Abstract

Reactions of quinquedentate Schiff base ligands with Mn and Cu ions afforded icosa- and hexadecanuclear mixed-metal clusters in which dinuclear CuII complexes trapped oxo-bridged [MnIII 8MnIV4O12] and [Mn III6O6] cores, respectively. Maximum entropy method analysis for synchrotron X-ray diffraction data was used to determine the oxidation states of the Mn ions.

Original languageEnglish
Pages (from-to)3810-3812
Number of pages3
JournalInorganic chemistry
Volume46
Issue number10
DOIs
Publication statusPublished - 2007 May 14

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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