Magnetization of (ET)2- and κ-(BETS)2-FeCl4

H. Uozaki, K. Okamoto, S. Endo, H. Matsui, K. Ueda, T. Sugimoto, N. Toyota

Research output: Contribution to journalConference article

8 Citations (Scopus)

Abstract

Both (ET)2FeCl4 and κ-(BETS)2FeCl4 have Fe3+ ions in the anion layer. The former is a semiconductor with an energy gap of 0.12 eV and the latter remains normal metallic down to below 0.5 K. Their magnetizations, which are very similar to each other, are scaled by the Brillouin function (S=5/2) modified by the effective temperature T*=T-Θ. The Weiss temperature Θ is estimated to be -3 K and -1 K for ET and BETS salts, respectively. Both systems are concluded to have the high spin states (S=5/2) of Fe3+ ions which are antiferromagnetically interacting each other very weakly.

Original languageEnglish
Number of pages1
JournalSynthetic Metals
Volume103
Issue number1-3
DOIs
Publication statusPublished - 1999 Jun 24
Externally publishedYes
EventProceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier
Duration: 1998 Jul 121998 Jul 18

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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    Uozaki, H., Okamoto, K., Endo, S., Matsui, H., Ueda, K., Sugimoto, T., & Toyota, N. (1999). Magnetization of (ET)2- and κ-(BETS)2-FeCl4. Synthetic Metals, 103(1-3). https://doi.org/10.1016/S0379-6779(98)00910-2