Magnetization-induced second harmonic generation in a three-dimensional manganese octacyanoniobate-based pyroelectric ferrimagnet

Yoshihide Tsunobuchi, Wataru Kosaka, Tomohiro Nuida, Shin Ichi Ohkoshi

Research output: Contribution to journalArticlepeer-review

29 Citations (Scopus)

Abstract

The magnetization-induced second harmonic generation (MSHG) is observed using a three-dimensional MnII-NbIV pyroelectric ferrimagnet, [{MnII(H2O)2}{Mn II(pyrazine)(H2O)2}{NbIV(CN) 8}]·4H2O, in which electric polarization is along the b-axis and the magnetic easy axis is along the a-axis. The SH intensity gradually increases due to superparamagnetism below 90 K, and then rapidly increases near the Curie temperature (TC = 48 K) due to spontaneous magnetization.

Original languageEnglish
Pages (from-to)2051-2053
Number of pages3
JournalCrystEngComm
Volume11
Issue number10
DOIs
Publication statusPublished - 2009 Sep 29
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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