Magnetization-induced second harmonic generation in a three-dimensional manganese octacyanoniobate-based pyroelectric ferrimagnet

Yoshihide Tsunobuchi; Wataru Kosaka; Tomohiro Nuida; Shin Ichi Ohkoshi

doi:10.1039/b906778g

Magnetization-induced second harmonic generation in a three-dimensional manganese octacyanoniobate-based pyroelectric ferrimagnet

Yoshihide Tsunobuchi, Wataru Kosaka, Tomohiro Nuida, Shin Ichi Ohkoshi

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

The magnetization-induced second harmonic generation (MSHG) is observed using a three-dimensional Mn^II-Nb^IV pyroelectric ferrimagnet, [{Mn^II(H₂O)₂}{Mn ^II(pyrazine)(H₂O)₂}{Nb^IV(CN) ₈}]·4H₂O, in which electric polarization is along the b-axis and the magnetic easy axis is along the a-axis. The SH intensity gradually increases due to superparamagnetism below 90 K, and then rapidly increases near the Curie temperature (T_C = 48 K) due to spontaneous magnetization.

Original language	English
Pages (from-to)	2051-2053
Number of pages	3
Journal	CrystEngComm
Volume	11
Issue number	10
DOIs	https://doi.org/10.1039/b906778g
Publication status	Published - 2009 Sep 29
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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abstract = "The magnetization-induced second harmonic generation (MSHG) is observed using a three-dimensional MnII-NbIV pyroelectric ferrimagnet, [{MnII(H2O)2}{Mn II(pyrazine)(H2O)2}{NbIV(CN) 8}]·4H2O, in which electric polarization is along the b-axis and the magnetic easy axis is along the a-axis. The SH intensity gradually increases due to superparamagnetism below 90 K, and then rapidly increases near the Curie temperature (TC = 48 K) due to spontaneous magnetization.",

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AU - Tsunobuchi, Yoshihide

AU - Kosaka, Wataru

AU - Nuida, Tomohiro

AU - Ohkoshi, Shin Ichi

PY - 2009/9/29

Y1 - 2009/9/29

N2 - The magnetization-induced second harmonic generation (MSHG) is observed using a three-dimensional MnII-NbIV pyroelectric ferrimagnet, [{MnII(H2O)2}{Mn II(pyrazine)(H2O)2}{NbIV(CN) 8}]·4H2O, in which electric polarization is along the b-axis and the magnetic easy axis is along the a-axis. The SH intensity gradually increases due to superparamagnetism below 90 K, and then rapidly increases near the Curie temperature (TC = 48 K) due to spontaneous magnetization.

AB - The magnetization-induced second harmonic generation (MSHG) is observed using a three-dimensional MnII-NbIV pyroelectric ferrimagnet, [{MnII(H2O)2}{Mn II(pyrazine)(H2O)2}{NbIV(CN) 8}]·4H2O, in which electric polarization is along the b-axis and the magnetic easy axis is along the a-axis. The SH intensity gradually increases due to superparamagnetism below 90 K, and then rapidly increases near the Curie temperature (TC = 48 K) due to spontaneous magnetization.

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Magnetization-induced second harmonic generation in a three-dimensional manganese octacyanoniobate-based pyroelectric ferrimagnet

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