Magnetic/conducting bifunctionality due to π/σ-conjugated functional moieties in a stacked ferrimagnetic chain

Hitoshi Miyasaka, Yuichiro Asai, Natsuko Motokawa, Kazuya Kubo, Masahiro Yamashita

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

An alternating chain of a paddlewheel [Ru2 II,III(O2CEt)4]+ (EtCO 2- = propionate) complex and [Pt(mnt)2] - (mnt2- = maleonitriledithiolate) has a ferrimagnetic spin arrangement of S = 3/2 and 1/2 local spins, respectively, as well as three-dimensional antiferromagnetic ordering with a canting mode at 8.6 K. This chain is stacked at the [Pt(mnt)2]- units to form a slipped column in the vertical direction against the chain, which acts as a pathway for electrical conduction.

Original languageEnglish
Pages (from-to)9116-9118
Number of pages3
JournalInorganic chemistry
Volume49
Issue number20
DOIs
Publication statusPublished - 2010 Oct 18

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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