Magnetic switching by desorption/adsorption of an organic solvent molecule from/on [Ni(dmit) 2 ] 1 salt

Katsuya Ichihashi, Takumi Nishimura, Daisuke Konno, Katsuya Inoue, Toshimi Nakaya, Tomoyuki Akutagawa, Takayoshi Nakamura, Sadafumi Nishihara

Research output: Contribution to journalArticlepeer-review

Abstract

Herein, the synthesis and physical properties of a monovalent [Ni(dmit) 2 ] 1 salt (dmit 21 = 2-thioxo-1,3-dithiole-4,5-dithiolate) containing a supramolecular cation composed of Na + ions, dibenzo[18]crown-6 molecules, and CH 3 CN molecules, has been reported. The desorption/adsorption of CH 3 CN molecules (organic solvent molecules) from/on the [Ni(dmit) 2 ] 1 salt occurred while maintaining the crystalline state and could be utilized to switch the magnetic properties of the salt.

Original languageEnglish
Pages (from-to)329-332
Number of pages4
JournalChemistry Letters
Volume48
Issue number4
DOIs
Publication statusPublished - 2019 Jan 1

Keywords

  • Desorption/adsorption
  • Magnetic switching
  • [Ni(dmit) ]

ASJC Scopus subject areas

  • Chemistry(all)

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