Magnetic switching by desorption/adsorption of an organic solvent molecule from/on [Ni(dmit)                         2                         ]                         1                          salt

Katsuya Ichihashi; Takumi Nishimura; Daisuke Konno; Katsuya Inoue; Toshimi Nakaya; Tomoyuki Akutagawa; Takayoshi Nakamura; Sadafumi Nishihara

doi:10.1246/cl.181031

Magnetic switching by desorption/adsorption of an organic solvent molecule from/on [Ni(dmit) ₂ ] ¹ salt

Katsuya Ichihashi, Takumi Nishimura, Daisuke Konno, Katsuya Inoue, Toshimi Nakaya, Tomoyuki Akutagawa, Takayoshi Nakamura, Sadafumi Nishihara

Polymer Hybrid Materials Research Center

Research output: Contribution to journal › Article › peer-review

Abstract

Herein, the synthesis and physical properties of a monovalent [Ni(dmit) ₂ ] ¹ salt (dmit ²¹ = 2-thioxo-1,3-dithiole-4,5-dithiolate) containing a supramolecular cation composed of Na ⁺ ions, dibenzo[18]crown-6 molecules, and CH ₃ CN molecules, has been reported. The desorption/adsorption of CH ₃ CN molecules (organic solvent molecules) from/on the [Ni(dmit) ₂ ] ¹ salt occurred while maintaining the crystalline state and could be utilized to switch the magnetic properties of the salt.

Original language	English
Pages (from-to)	329-332
Number of pages	4
Journal	Chemistry Letters
Volume	48
Issue number	4
DOIs	https://doi.org/10.1246/cl.181031
Publication status	Published - 2019 Jan 1

Keywords

Desorption/adsorption
Magnetic switching
[Ni(dmit) ]

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/cl.181031

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Ichihashi, K., Nishimura, T., Konno, D., Inoue, K., Nakaya, T., Akutagawa, T., Nakamura, T., & Nishihara, S. (2019). Magnetic switching by desorption/adsorption of an organic solvent molecule from/on [Ni(dmit) ₂ ] ¹ salt Chemistry Letters, 48(4), 329-332. https://doi.org/10.1246/cl.181031

Magnetic switching by desorption/adsorption of an organic solvent molecule from/on [Ni(dmit) ₂ ] ¹ salt . / Ichihashi, Katsuya; Nishimura, Takumi; Konno, Daisuke; Inoue, Katsuya; Nakaya, Toshimi; Akutagawa, Tomoyuki; Nakamura, Takayoshi; Nishihara, Sadafumi.

In: Chemistry Letters, Vol. 48, No. 4, 01.01.2019, p. 329-332.

Research output: Contribution to journal › Article › peer-review

Ichihashi, K, Nishimura, T, Konno, D, Inoue, K, Nakaya, T, Akutagawa, T, Nakamura, T & Nishihara, S 2019, ' Magnetic switching by desorption/adsorption of an organic solvent molecule from/on [Ni(dmit) ₂ ] ¹ salt ', Chemistry Letters, vol. 48, no. 4, pp. 329-332. https://doi.org/10.1246/cl.181031

Ichihashi K, Nishimura T, Konno D, Inoue K, Nakaya T, Akutagawa T et al. Magnetic switching by desorption/adsorption of an organic solvent molecule from/on [Ni(dmit) ₂ ] ¹ salt Chemistry Letters. 2019 Jan 1;48(4):329-332. https://doi.org/10.1246/cl.181031

Ichihashi, Katsuya ; Nishimura, Takumi ; Konno, Daisuke ; Inoue, Katsuya ; Nakaya, Toshimi ; Akutagawa, Tomoyuki ; Nakamura, Takayoshi ; Nishihara, Sadafumi. / Magnetic switching by desorption/adsorption of an organic solvent molecule from/on [Ni(dmit) ₂ ] ¹ salt In: Chemistry Letters. 2019 ; Vol. 48, No. 4. pp. 329-332.

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AB - Herein, the synthesis and physical properties of a monovalent [Ni(dmit) 2 ] 1 salt (dmit 21 = 2-thioxo-1,3-dithiole-4,5-dithiolate) containing a supramolecular cation composed of Na + ions, dibenzo[18]crown-6 molecules, and CH 3 CN molecules, has been reported. The desorption/adsorption of CH 3 CN molecules (organic solvent molecules) from/on the [Ni(dmit) 2 ] 1 salt occurred while maintaining the crystalline state and could be utilized to switch the magnetic properties of the salt.

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