Abstract
Herein, the synthesis and physical properties of a monovalent [Ni(dmit) 2 ] 1 salt (dmit 21 = 2-thioxo-1,3-dithiole-4,5-dithiolate) containing a supramolecular cation composed of Na + ions, dibenzo[18]crown-6 molecules, and CH 3 CN molecules, has been reported. The desorption/adsorption of CH 3 CN molecules (organic solvent molecules) from/on the [Ni(dmit) 2 ] 1 salt occurred while maintaining the crystalline state and could be utilized to switch the magnetic properties of the salt.
Original language | English |
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Pages (from-to) | 329-332 |
Number of pages | 4 |
Journal | Chemistry Letters |
Volume | 48 |
Issue number | 4 |
DOIs | |
Publication status | Published - 2019 Jan 1 |
Keywords
- Desorption/adsorption
- Magnetic switching
- [Ni(dmit) ]
ASJC Scopus subject areas
- Chemistry(all)