Magnetic switching by desorption/adsorption of an organic solvent molecule from/on [Ni(dmit) 2 ] 1 salt

Katsuya Ichihashi, Takumi Nishimura, Daisuke Konno, Katsuya Inoue, Toshimi Nakaya, Tomoyuki Akutagawa, Takayoshi Nakamura, Sadafumi Nishihara

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Herein, the synthesis and physical properties of a monovalent [Ni(dmit) 2 ] 1 salt (dmit 21 = 2-thioxo-1,3-dithiole-4,5-dithiolate) containing a supramolecular cation composed of Na + ions, dibenzo[18]crown-6 molecules, and CH 3 CN molecules, has been reported. The desorption/adsorption of CH 3 CN molecules (organic solvent molecules) from/on the [Ni(dmit) 2 ] 1 salt occurred while maintaining the crystalline state and could be utilized to switch the magnetic properties of the salt.

    Original languageEnglish
    Pages (from-to)329-332
    Number of pages4
    JournalChemistry Letters
    Volume48
    Issue number4
    DOIs
    Publication statusPublished - 2019

    Keywords

    • Desorption/adsorption
    • Magnetic switching
    • [Ni(dmit) ]

    ASJC Scopus subject areas

    • Chemistry(all)

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