@article{a30b2a3276f74c4e84dc8227acaf49dd,
title = " Magnetic switching by desorption/adsorption of an organic solvent molecule from/on [Ni(dmit) 2 ] 1 salt ",
abstract = " Herein, the synthesis and physical properties of a monovalent [Ni(dmit) 2 ] 1 salt (dmit 21 = 2-thioxo-1,3-dithiole-4,5-dithiolate) containing a supramolecular cation composed of Na + ions, dibenzo[18]crown-6 molecules, and CH 3 CN molecules, has been reported. The desorption/adsorption of CH 3 CN molecules (organic solvent molecules) from/on the [Ni(dmit) 2 ] 1 salt occurred while maintaining the crystalline state and could be utilized to switch the magnetic properties of the salt. ",
keywords = "Desorption/adsorption, Magnetic switching, [Ni(dmit) ]",
author = "Katsuya Ichihashi and Takumi Nishimura and Daisuke Konno and Katsuya Inoue and Toshimi Nakaya and Tomoyuki Akutagawa and Takayoshi Nakamura and Sadafumi Nishihara",
note = "Funding Information: This study was supported by a Grant-in-Aid for Scientific Research on Japan Society for the Promotion of Science (JSPS); KAKENHI (Nos. JP16H04223, JP16K14101, JP24350095, JP25220803, and JP17J02578); and the JSPS Core-to-Core Program, A. Advanced Research Networks. This work was also performed under the aegis of the Canon Science Promotion Foundation, Murata Science Foundation, Casio Science Promotion Foundation, and a Cooperative Research Program of {\textquoteleft}Network Joint Research Center for Materials and Devices.{\textquoteright} This work was partly supported by Nanotechnology Platform Program (Molecule and Material Synthesis) of the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan. We thank Ms. M. Kubota and Dr. Y. Mouri, the Natural Science Center for Basic Research and Development (N-BARD), Hiroshima University, for performing the elemental analyses. Single-crystal XRD measurement was carried out using a Bruker SMART APEX-II ULTRA diffractometer at N-BARD, Hiroshima University. Publisher Copyright: {\textcopyright} 2019 The Chemical Society of Japan",
year = "2019",
doi = "10.1246/cl.181031",
language = "English",
volume = "48",
pages = "329--332",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "Chemical Society of Japan",
number = "4",
}