Magnetic relaxation of single-molecule magnets in an external magnetic field: An ising dimer of a terbium(III)-phthalocyaninate triple-decker complex

Keiichi Katoh, Takashi Kajiwara, Motohiro Nakano, Yasuhiro Nakazawa, Wolfgang Wernsdorfer, Naoto Ishikawa, Brian K. Breedlove, Masahiro Yamashita

Research output: Contribution to journalArticlepeer-review

105 Citations (Scopus)

Abstract

A single magnet in a triple decker! TbIII-phthalocyaninate triple-decker 1, which has a center of symmetry, showed two magnetic relaxation processes in the low-temperature region in the presence of a direct current (dc) magnetic field. These results suggest that the single-molecule magnet/magnetic properties of 1 undergo a significant transition in a dc magnetic field.

Original languageEnglish
Pages (from-to)117-122
Number of pages6
JournalChemistry - A European Journal
Volume17
Issue number1
DOIs
Publication statusPublished - 2011 Jan 3

Keywords

  • lanthanoids
  • ligand field theory
  • magnetic properties
  • phthalocyanines
  • single-molecule magnets

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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