Abstract
Search for an organic ferrimagnet has been one of the challenging targets in the field of material science. Recently, we have reported the successful results for the crystals of a novel organic triradical of 2-[3′,5′-bis(N-tert-butylaminoxyl)phenyl]-4,4,5,5-tetramethyl-4,5-di hydro-1H-imidazol-1-oxyl-3-oxide (PNNBNO). This is the first example of a genuine organic ferrimagnetic material having well-defined chemical and crystal structure with TC=0.28K. The properties of PNNBNO are described and the magnetic interactions of this system are discussed in comparison with the related oligoaminoxyl radicals.
| Original language | English |
|---|---|
| Pages (from-to) | 527-530 |
| Number of pages | 4 |
| Journal | Synthetic Metals |
| Volume | 133-134 |
| DOIs | |
| Publication status | Published - 2003 Mar 13 |
| Externally published | Yes |
| Event | ISCOM 2001 - Rusutsu, Hokkaido, Japan Duration: 2001 Sep 10 → 2001 Sep 14 |
Keywords
- Aminoxyl
- Ferrimagnetism
- Ladder
- Organic radical
- Single-component
- Triradical
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Condensed Matter Physics
- Mechanics of Materials
- Mechanical Engineering
- Metals and Alloys
- Materials Chemistry