TY - JOUR
T1 - Magnetic Properties of Some Triangular Trinuclear Complexes of [Ru2M(μ-CH3COO)6(μ 3-O)(py)3]n+ with a Paramagnetic Ion M
AU - Kobayashi, Hanako
AU - Uryû, Norikiyo
AU - Mogi, Iwao
AU - Miyamoto, Ryo
AU - Ohba, Yasunori
AU - Iwaizumi, Masamoto
AU - Sasaki, Yoichi
AU - Ohto, Akihiro
AU - Suwabe, Masaaki
AU - Ito, Tasuku
PY - 1996/11
Y1 - 1996/11
N2 - Magnetic susceptibilities and electron paramagnetic resonances (EPRs) of coordination compounds of triangular trinuclear [Ru2M(μ-CH3COO)6(μ 3-O)(py)3]n+, M=Mn(II), Fe(III), Cr(III), Ni(II), or Co(II) ions, were observed. The results were analysed by the spin vector model. Effective Bohr magneton numbers showed that the main superexchange interaction within each cluster was of the order of J/k=-300 K. This was considered to be working through μ3-O. Together with some weaker superexchange interactions through μ-CH3COO paths, fittings with the susceptibilities of the model were tried. EPR signals at temperatures of a few K were characteristic of each M ion. M=Mn(II) and M=Fe(III) were at high spin states of S=5/2 and M=Co(II) was at a low spin state of S=1/2. Temperature dependences of EPR signals are discussed.
AB - Magnetic susceptibilities and electron paramagnetic resonances (EPRs) of coordination compounds of triangular trinuclear [Ru2M(μ-CH3COO)6(μ 3-O)(py)3]n+, M=Mn(II), Fe(III), Cr(III), Ni(II), or Co(II) ions, were observed. The results were analysed by the spin vector model. Effective Bohr magneton numbers showed that the main superexchange interaction within each cluster was of the order of J/k=-300 K. This was considered to be working through μ3-O. Together with some weaker superexchange interactions through μ-CH3COO paths, fittings with the susceptibilities of the model were tried. EPR signals at temperatures of a few K were characteristic of each M ion. M=Mn(II) and M=Fe(III) were at high spin states of S=5/2 and M=Co(II) was at a low spin state of S=1/2. Temperature dependences of EPR signals are discussed.
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U2 - 10.1246/bcsj.69.3163
DO - 10.1246/bcsj.69.3163
M3 - Article
AN - SCOPUS:0003475925
VL - 69
SP - 3163
EP - 3172
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
SN - 0009-2673
IS - 11
ER -