Magnetic Circular Dichroism Studies on [5,10,15,20-Tetrakis(l-methylpyridinium-4-yl)porphinato]iron and Some of Its Derivatives

Nagao Kobayashi, Masami Koshiyama, Tetsuo Osa, Theodore Kuwana

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25 Citations (Scopus)

Abstract

Magnetic circular dichroism (MCD) spectra are reported for [5,10,15,20-tetrakis(l-methylpyridinium-4-yl)porphinato]iron(III) and -iron(II), FeIII TMP and FeIITMP, and some of their derivatives in the near-UV to near-IR regions. Two proton equilibria existed between the three FeIIITMP monomers with pKa values of ca. 5.7 and 12.3 while, after electrochemical reduction, an equilibrium was observed between the two FeIITMP monomers with a pKa of ca. 11.2. The species were in high-spin states except FeIIITMP at pH >13 and FeIITMP at pH >12 (low spin). Porphyrin electronic structures of the coordination spheres on these species and their bis(imidazole) and bis(cyanide) derivatives are discussed in comparison with information on iron porphyrins and hemes previously studied.

Original languageEnglish
Pages (from-to)3608-3614
Number of pages7
JournalInorganic chemistry
Volume22
Issue number24
DOIs
Publication statusPublished - 1983 Nov

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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