Luminescence of fusion materials of polymeric chain-structured lanthanide complexes

Saki Sato, Ayumi Ishii, Chisaki Yamada, Junguen Kim, Chul Ho Song, Akihiko Fujiwara, Masaki Takata, Miki Hasegawa

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

Polymeric chain-structured complexes were prepared with helical lanthanide complexes (LnL; Ln=Eu III, Tb III, Gd III) and benzene-dicarboxylate derivatives (benzene-1,4-dicarboxylate (bdc), 2-aminoterephtalate (atpa) and 2-hydoloxyterephtalate (htpa)), which show some noteworthy physicochemical properties, photoluminescence and thermal stabilities. The complex EuL-bdc shows bright luminescence originating from Eu III by UV excitation. The emission color can be tuned by mixing with TbL. The structures of these chain complexes were clarified with synchrotron X-ray powder diffraction measurements. The derivation of the linker moiety (bdc, atpa or htpa) was found to affect the intermetal energy transfer from Tb III to Eu III.

Original languageEnglish
Pages (from-to)195-200
Number of pages6
JournalPolymer Journal
Volume47
Issue number2
DOIs
Publication statusPublished - 2015 Feb 7
Externally publishedYes

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

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