Long-lived charge-separated state produced by photoinduced electron transfer in a zinc imidazoporphyrin-C60 dyad

Yukiyasu Kashiwagi; Kei Ohkubo; James A. McDonald; Iain M. Blake; Maxwell J. Crossley; Yasuyuki Araki; Osamu Ito; Hiroshi Imahori; Shunichi Fukuzumi

doi:10.1021/ol0349256

Long-lived charge-separated state produced by photoinduced electron transfer in a zinc imidazoporphyrin-C₆₀ dyad

Yukiyasu Kashiwagi, Kei Ohkubo, James A. McDonald, Iain M. Blake, Maxwell J. Crossley, Yasuyuki Araki, Osamu Ito, Hiroshi Imahori, Shunichi Fukuzumi

Division of Organic- and Biomaterials Research

Research output: Contribution to journal › Article › peer-review

99 Citations (Scopus)

Abstract

(Matrix presented) Photoexcitation of a zinc imidazoporphyrin-fullerene dyad with a short linkage results in formation of the charge-separated state by photoinduced electron transfer. The charge-separated state has a lifetime of 310 μs in benzonitrile at 278 K, which is the longest lifetime in solution ever reported for electron donor-acceptor-linked dyads.

Original language	English
Pages (from-to)	2719-2721
Number of pages	3
Journal	Organic letters
Volume	5
Issue number	15
DOIs	https://doi.org/10.1021/ol0349256
Publication status	Published - 2003 Jul 24

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol0349256

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abstract = "(Matrix presented) Photoexcitation of a zinc imidazoporphyrin-fullerene dyad with a short linkage results in formation of the charge-separated state by photoinduced electron transfer. The charge-separated state has a lifetime of 310 μs in benzonitrile at 278 K, which is the longest lifetime in solution ever reported for electron donor-acceptor-linked dyads.",

author = "Yukiyasu Kashiwagi and Kei Ohkubo and McDonald, {James A.} and Blake, {Iain M.} and Crossley, {Maxwell J.} and Yasuyuki Araki and Osamu Ito and Hiroshi Imahori and Shunichi Fukuzumi",

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AU - Kashiwagi, Yukiyasu

AU - Ohkubo, Kei

AU - McDonald, James A.

AU - Blake, Iain M.

AU - Crossley, Maxwell J.

AU - Araki, Yasuyuki

AU - Ito, Osamu

AU - Imahori, Hiroshi

AU - Fukuzumi, Shunichi

PY - 2003/7/24

Y1 - 2003/7/24

N2 - (Matrix presented) Photoexcitation of a zinc imidazoporphyrin-fullerene dyad with a short linkage results in formation of the charge-separated state by photoinduced electron transfer. The charge-separated state has a lifetime of 310 μs in benzonitrile at 278 K, which is the longest lifetime in solution ever reported for electron donor-acceptor-linked dyads.

AB - (Matrix presented) Photoexcitation of a zinc imidazoporphyrin-fullerene dyad with a short linkage results in formation of the charge-separated state by photoinduced electron transfer. The charge-separated state has a lifetime of 310 μs in benzonitrile at 278 K, which is the longest lifetime in solution ever reported for electron donor-acceptor-linked dyads.

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Long-lived charge-separated state produced by photoinduced electron transfer in a zinc imidazoporphyrin-C₆₀ dyad

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