Local chemical reaction of benzene on Cu(10) via STM-induced excitation

T. Komeda, Y. Kim, Y. Fujita, Y. Sainoo, Maki Kawai

Research output: Contribution to journalArticlepeer-review

87 Citations (Scopus)

Abstract

The mechanism for the tunneling electron-induced chemical reaction of benzene molecules on Cu(110) was examined. The increase in the height of benzene molecule by 40% was detected with the dosing of tunneling electrons of the energy 2-5 eV from the scanning tunneling microscope (STM) tip to the molecule. For the negative sample voltage up to 5 eV, no increase of the reaction yield was observed. The results show a sharp rise of the reaction probability at the sample bias voltage at 2.4 V, which saturates at 3.0 V.

Original languageEnglish
Pages (from-to)5347-5352
Number of pages6
JournalJournal of Chemical Physics
Volume120
Issue number11
DOIs
Publication statusPublished - 2004 Mar 15

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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