Local and average structure of lead titanate based ceramics

J. Frantti; S. Ivanov; J. Lappalainen; S. Eriksson; V. Lantto; S. Nishio; M. Kakihana; H. Rundlöf

doi:10.1080/00150190211446

Local and average structure of lead titanate based ceramics

J. Frantti, S. Ivanov, J. Lappalainen, S. Eriksson, V. Lantto, S. Nishio, M. Kakihana, H. Rundlöf

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The revised lattice dynamics of Pb(Zr_xTi_1-x)O 3 (PZT) with 0.10 ≤ x ≤ 0.54 ceramics is reported. The phase transition from tetragonal phase to the monoclinic phase is proposed to occur via locally distorted regions. Neutron diffraction data suggests that these local regions transform to the monoclinic phase with decreasing temperature, when x ≈ 0.50.

Original language	English
Pages (from-to)	73-90
Number of pages	18
Journal	Ferroelectrics
Volume	266
DOIs	https://doi.org/10.1080/00150190211446
Publication status	Published - 2002 Jan 1
Externally published	Yes

Keywords

Lead Zirconate Titanate
Local Structure
Neutron Diffraction
Raman Spectroscopy
Rare Earth

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics

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10.1080/00150190211446

Cite this

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title = "Local and average structure of lead titanate based ceramics",

abstract = "The revised lattice dynamics of Pb(ZrxTi1-x)O 3 (PZT) with 0.10 ≤ x ≤ 0.54 ceramics is reported. The phase transition from tetragonal phase to the monoclinic phase is proposed to occur via locally distorted regions. Neutron diffraction data suggests that these local regions transform to the monoclinic phase with decreasing temperature, when x ≈ 0.50.",

keywords = "Lead Zirconate Titanate, Local Structure, Neutron Diffraction, Raman Spectroscopy, Rare Earth",

author = "J. Frantti and S. Ivanov and J. Lappalainen and S. Eriksson and V. Lantto and S. Nishio and M. Kakihana and H. Rundl{\"o}f",

note = "Funding Information: We wish to thank Dr. S. Stephanovich for carrying out the Second-Harmonic-Generation measurements. One of the authors (J. F.) is grateful to the Graduate School in Electronics, Telecommunication and Automation (GETA at the Helsinki University of Technology), the University of Oulu Foundation and the Academy of Finland for financial support (Project numbers 39189 and 72196). This work is supported by Grant-in-Aid for Scientific Research No. 11450246.",

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doi = "10.1080/00150190211446",

language = "English",

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journal = "Ferroelectrics",

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T1 - Local and average structure of lead titanate based ceramics

AU - Frantti, J.

AU - Ivanov, S.

AU - Lappalainen, J.

AU - Eriksson, S.

AU - Lantto, V.

AU - Nishio, S.

AU - Kakihana, M.

AU - Rundlöf, H.

N1 - Funding Information: We wish to thank Dr. S. Stephanovich for carrying out the Second-Harmonic-Generation measurements. One of the authors (J. F.) is grateful to the Graduate School in Electronics, Telecommunication and Automation (GETA at the Helsinki University of Technology), the University of Oulu Foundation and the Academy of Finland for financial support (Project numbers 39189 and 72196). This work is supported by Grant-in-Aid for Scientific Research No. 11450246.

PY - 2002/1/1

Y1 - 2002/1/1

N2 - The revised lattice dynamics of Pb(ZrxTi1-x)O 3 (PZT) with 0.10 ≤ x ≤ 0.54 ceramics is reported. The phase transition from tetragonal phase to the monoclinic phase is proposed to occur via locally distorted regions. Neutron diffraction data suggests that these local regions transform to the monoclinic phase with decreasing temperature, when x ≈ 0.50.

AB - The revised lattice dynamics of Pb(ZrxTi1-x)O 3 (PZT) with 0.10 ≤ x ≤ 0.54 ceramics is reported. The phase transition from tetragonal phase to the monoclinic phase is proposed to occur via locally distorted regions. Neutron diffraction data suggests that these local regions transform to the monoclinic phase with decreasing temperature, when x ≈ 0.50.

KW - Lead Zirconate Titanate

KW - Local Structure

KW - Neutron Diffraction

KW - Raman Spectroscopy

KW - Rare Earth

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EP - 90

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JF - Ferroelectrics

SN - 0015-0193

ER -

Local and average structure of lead titanate based ceramics

Abstract

Keywords

ASJC Scopus subject areas

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